Extra 20 important long-answer questions from the "Structure of the Atom" chapter:4 of Class 9 CBSE Science:-
1. Explain Dalton’s Atomic Theory and its limitations.
Answer: Dalton proposed the first atomic theory:
All matter is made of tiny, indivisible particles called atoms.
Atoms of the same element are identical in mass and properties.
Atoms of different elements differ in mass and properties.
Atoms combine in simple whole-number ratios to form compounds.
Chemical reactions involve the rearrangement of atoms.
Limitations:
Atoms are divisible (discovery of protons, neutrons, and electrons).
Isotopes exist (same element, different mass numbers).
Atoms can change in nuclear reactions.
2. Describe Rutherford’s gold foil experiment and its conclusions.
Answer:
Rutherford bombarded thin gold foil with alpha (α) particles.
Most particles passed through, some deflected, and few bounced back.
This led to the discovery of the
nucleus
in an atom.
Conclusions:
Atom has a
small, dense, positively charged nucleus
.
Electrons revolve around the nucleus in empty space.
Most of the atom is empty space.
Limitations:
Could not explain electron stability.
Did not describe the arrangement of electrons.
3. State Bohr’s atomic model and its advantages.
Answer:
Electrons revolve in
fixed energy levels (shells)
around the nucleus.
Electrons do not lose energy while revolving.
Energy is absorbed or emitted when electrons jump between levels.
The energy of an orbit is
quantized
.
The
maximum number of electrons in a shell
follows the
2n²
rule.
Advantages:
Explained atomic stability.
Justified hydrogen’s spectral lines.
Introduced the concept of quantized energy levels.
4. Differentiate between Isotopes and Isobars with examples.
Answer:
Property |
Isotopes |
Isobars |
---|---|---|
Definition |
Atoms of the same element with different mass numbers |
Atoms of different elements with the same mass number |
Atomic Number |
Same |
Different |
Mass Number |
Different |
Same |
Examples |
Carbon-12, Carbon-14 |
Argon-40, Calcium-40 |
5. Define valency. How is it determined? Give examples.
Answer:
Valency
is the combining capacity of an element.
It is determined by the number of electrons
lost, gained, or shared
.
If an element
loses electrons
, valency = number of lost electrons.
If it
gains electrons
, valency = number of gained electrons.
Example: Na (2,8,1) loses 1 electron, so valency = 1.
Cl (2,8,7) gains 1 electron, so valency = 1.
6. Explain the discovery of electrons, protons, and neutrons.
Answer:
Electron (J.J. Thomson, 1897)
: Cathode ray experiment.
Proton (Goldstein, 1886)
: Canal ray experiment.
Neutron (James Chadwick, 1932)
: Bombarded beryllium with alpha particles.
7. What is the electronic configuration? Explain with an example.
Answer:
Electronic configuration
is the arrangement of electrons in shells.
It follows the
2n²
rule.
Example: Sodium (Z=11) →
2,8,1
.
The last shell determines valency.
Noble gases
have a complete outer shell (stable configuration).
8. Compare Rutherford’s and Bohr’s models of the atom.
Answer:
Feature |
Rutherford’s Model |
Bohr’s Model |
---|---|---|
Electron Path |
Random motion |
Fixed orbits |
Energy Loss |
Predicted loss |
No energy loss |
Stability |
Could not explain |
Explained |
Nucleus |
Present |
Present |
Energy Levels |
Not defined |
Quantized |
9. Explain the concept of atomic number and mass number.
Answer:
Atomic number (Z)
= Number of protons = Number of electrons.
Mass number (A)
= Protons + Neutrons.
Example: Oxygen (Z=8, A=16) has 8 protons and 8 neutrons.
Atomic number determines the element’s identity.
10. Describe the structure of an atom with a labelled diagram.
Answer:
Atom has
a central nucleus
containing protons and neutrons.
Electrons
revolve around the nucleus
in shells.
The
first shell (K) holds 2 electrons, L holds 8, M holds 18
, etc.
The
nucleus is positively charged
, and the atom is neutral.
11. Explain J.J. Thomson’s Model of an Atom. What were its limitations?
Answer:
J.J. Thomson proposed the
Plum Pudding Model
in 1897.
Atoms consist of a positively charged sphere with negatively charged electrons embedded in it.
The positive charge balances the negative charge, making the atom neutral.
Electrons were thought to be like "plums" in a positively charged "pudding."
The model explained the neutrality of atoms.
Limitations:
6. It could not explain the presence of a nucleus.
7. It failed to explain how electrons were arranged in an atom.
12. Describe the properties of cathode rays and how their discovery led to the identification of electrons.
Answer:
Cathode rays
were discovered by
J.J. Thomson
using a discharge tube experiment.
Cathode rays originate from the
negative electrode (cathode)
in a vacuum tube.
They travel in
straight lines
and cast shadows.
They are
negatively charged
, as they were deflected towards a positive plate.
They produce a
mechanical effect
, rotating a light paddle wheel.
This led to the discovery of the
electron
, a negatively charged particle.
The charge-to-mass ratio (e/me/me/m) of an electron was calculated.
13. Explain the significance of neutrons in an atom.
Answer:
Neutrons were discovered by
James Chadwick in 1932
.
Neutrons have
no charge
(neutral) and are present in the nucleus.
They provide
stability
by reducing repulsion between protons.
The number of neutrons affects the
mass number
of an atom.
Elements with different numbers of neutrons are called
isotopes
.
Neutrons play a key role in
nuclear reactions
(e.g., fission and fusion).
Atoms with an unstable neutron-to-proton ratio become
radioactive
.
14. What are the limitations of Rutherford’s atomic model?
Answer:
Rutherford proposed that electrons move in
random orbits
around the nucleus.
According to classical physics, moving electrons should lose energy and
spiral into the nucleus
.
This would make atoms
unstable
, but atoms are actually stable.
It did not explain the arrangement of
electrons in energy levels
.
It could not explain the
line spectra of elements
.
It failed to address why electrons do not
fall into the nucleus
.
Bohr’s model later resolved these issues by introducing
energy levels
.
15. Explain the relationship between energy levels and the spectrum of an atom.
Answer:
Electrons occupy
specific energy levels
in an atom.
When an electron
absorbs energy
, it jumps to a
higher energy level
(excited state).
When it returns to a
lower energy level
, it
releases energy
as light.
The emitted light forms
spectral lines
, which are unique for each element.
This explains the
line spectra
observed in atomic emission spectra.
The energy of the emitted photons follows
Bohr’s equation
E=
hνE
=
hνE
=
hν
.
The spectra help identify
elements in stars and chemical samples
.
16. Explain the concept of quantum numbers and their significance.
Answer:
Quantum numbers describe the
position and energy
of electrons in an atom.
Principal quantum number (n)
: Indicates the
energy level
(K, L, M, N).
Azimuthal quantum number (l)
: Determines the
shape of the orbital
(s, p, d, f).
Magnetic quantum number (m)
: Describes the
orientation of the orbital
.
Spin quantum number (s)
: Determines the
spin direction
of the electron (+½ or -½).
They help understand
electronic configuration
and
chemical bonding
.
Quantum numbers explain the
periodic trends
in the periodic table.
17. How does the concept of valency help in chemical bonding?
Answer:
Valency
is the number of electrons an atom
gains, loses, or shares
.
Atoms with
1, 2, or 3 valence electrons
tend to
lose
them, forming
positive ions
.
Atoms with
5, 6, or 7 valence electrons
tend to
gain
electrons, forming
negative ions
.
Elements with a valency of
4
prefer to
share
electrons (e.g., carbon in methane).
Noble gases have a
valency of 0
because they have a
full outer shell
.
Valency determines the
types of bonds
(ionic, covalent).
It helps predict
chemical reactivity
and
compound formation
.
18. How do isotopes of an element differ in physical and chemical properties?
Answer:
Physical properties differ
because isotopes have different
mass numbers
.
Chemical properties remain similar
because they have the same
electronic configuration
.
Isotopes may have different
densities and boiling points
.
Radioactive isotopes
are unstable and decay over time (e.g., Carbon-14).
Applications
: Uranium-235 is used in nuclear reactors, while Carbon-14 is used for dating fossils.
Some isotopes are used in
medical treatments
, e.g., Cobalt-60 for cancer therapy.
Example
: Hydrogen has
three isotopes
– Protium (¹H), Deuterium (²H), and Tritium (³H).
19. Describe the formation of ions with examples.
Answer:
An
ion
is a charged particle formed when an atom gains or loses electrons.
Cation
(+
ve
ion) is formed when an atom
loses electrons
(e.g., Na → Na⁺ + e⁻).
Anion
(-
ve
ion) is formed when an
atom
gains electrons
(e.g., Cl + e⁻ → Cl⁻).
Metals usually form
cations
, while non-metals form
anions
.
Ionic bonds
are formed when cations and anions attract each other (e.g., NaCl).
Examples
:
Mg²⁺ forms when magnesium loses 2 electrons.
O²⁻ forms when oxygen gains 2 electrons.
Ions play an important role in
electrolysis and conductivity
.
20. Explain the stability of atoms based on electronic configuration.
Answer:
Atoms are stable when they have a
full outermost shell (octet rule)
.
Noble gases like
He, Ne,
Ar
are naturally stable due to their full shells.
Atoms with
incomplete outer shells
are unstable and react to form
bonds
.
Metals
lose electrons
to attain a noble gas configuration.
Non-metals
gain electrons
to complete their octet.
Carbon forms
covalent bonds
as it has four valence electrons.
The concept of stability explains
why elements form compounds
.